Controlling selectivity for dechlorination of poly(vinyl chloride) with (xantphos)RhCl-Reference-Cited by-同舟云学术

Controlling selectivity for dechlorination of poly(vinyl chloride) with (xantphos)RhCl

Published:2023 Issue:6 Volume:10 Page:2047-2052
ISSN:2051-6347
Container-title:Materials Horizons
language:en
Short-container-title:Mater. Horiz.

Author:

Bush Nancy G.¹^ORCID,Assefa Mikiyas K.¹^ORCID,Bac Selin²^ORCID,Mallikarjun Sharada Shaama¹²^ORCID,Fieser Megan E.¹³^ORCID

Affiliation:

1. Department of Chemistry, University of Southern California, Los Angeles, California 90089, USA

2. Department of Chemical Engineering and Materials Science, Mork Family, University of Southern California, Los Angeles, California 90089, USA

3. Wrigley Institute for Environmental Studies, University of Southern California, Los Angeles, California 90089, USA

Abstract

Reactions of poly(vinyl chloride) (PVC) with a rhodium catalyst and H-donors reveal how reaction conditions can impact the selectivity for chloride removal, with sodium formate showing the highest selectivity for hydrodechlorination.

Funder

U.S. Department of Energy

National Science Foundation

University of Southern California

Women in Science and Engineering, University of Southern California

Publisher

Royal Society of Chemistry (RSC)

Subject

Electrical and Electronic Engineering,Process Chemistry and Technology,Mechanics of Materials,General Materials Science

Link

http://pubs.rsc.org/en/content/articlepdf/2023/MH/D2MH01293F

Reference32 articles.

1. Catalytic processing of plastic waste on the rise

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