Conversion of waste poly(vinyl chloride) to branched polyethylene mediated by silylium ions-Reference-Cited by-同舟云学术

Conversion of waste poly(vinyl chloride) to branched polyethylene mediated by silylium ions

Published:2024 Issue:23 Volume:15 Page:8766-8774
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wood Zachary A.¹^ORCID,Castro Eunice C.¹,Nguyen Angelyn N.¹,Fieser Megan E.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of Southern California, Los Angeles, CA, 91706, USA

2. Wrigley Institute for Environment and Sustainability University of Southern California, Los Angeles, CA, 91706, USA

Abstract

Lewis acidic silylium ions are used to completely remove Cl from poly(vinyl chloride) (PVC) in clean and commercial products through hydrodechlorination. Reaction conditions were found to impact the branching in the resulting polyethylene (PE).

Funder

Energy Frontier Research Centers

National Institutes of Health

Arnold and Mabel Beckman Foundation

National Institute of Standards and Technology

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00130C

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