Packing of Russian doll clusters to form a nanometer-scale CsCl-type compound in a Cr–Zn–Sn complex metallic alloy-Reference-Cited by-同舟云学术

Packing of Russian doll clusters to form a nanometer-scale CsCl-type compound in a Cr–Zn–Sn complex metallic alloy

Published:2017 Issue:29 Volume:5 Page:7215-7221
ISSN:2050-7526
Container-title:Journal of Materials Chemistry C
language:en
Short-container-title:J. Mater. Chem. C

Author:

Xie Weiwei¹²³⁴^ORCID,Cava Robert J.¹⁵⁶⁴,Miller Gordon J.¹⁷⁸⁴

Affiliation:

1. Department of Chemistry

2. Louisiana State University

3. Baton Rouge

4. USA

5. Princeton University

6. Princeton

7. Iowa State University and Ames Laboratory

8. Ames

Abstract

A new cubic complex metallic alloy phase, Cr₂₂Zn₇₂Sn₂₄, with a lattice parameter near 2.5 nm was discovered in crystals grown using a Zn/Sn flux. The structure consists of Russian doll clusters or a 3-d network of Cr-centered icosahedra (shown) with bcc-metal fragments in void spaces.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/TC/C7TC01967J

Reference29 articles.

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