Alder-ene reactions driven by high steric strain and bond angle distortion to form benzocyclobutenes
Author:
Affiliation:
1. Department of Chemistry
2. University of Illinois at Chicago
3. Chicago
4. USA
5. College of Chemistry and Materials Engineering
6. Wenzhou University
7. Wenzhou
8. P. R. China
Abstract
A unique aryne-based Alder-ene reaction to form benzocyclobutene is described.
Funder
National Natural Science Foundation of China
National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC04277B
Reference50 articles.
1. A Comprehensive History of Arynes in Natural Product Total Synthesis
2. Arynes and Cyclohexyne in Natural Product Synthesis
3. Employing Arynes in Diels–Alder Reactions and Transition-Metal-Free Multicomponent Coupling and Arylation Reactions
4. Recent advances in molecular rearrangements involving aryne intermediates
5. Reactions of arynes promoted by silver ions
Cited by 29 articles. 订阅此论文施引文献 订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献
1. Regioselectively photoinduced synthesis, NMR analysis and X-ray crystal structure of novel benzocyclobutenes;Journal of Molecular Structure;2024-11
2. Selectivity in the Formal [2 + 2 + 2] Cycloaromatization of Enyne–Allenes Generated by the Alder-ene Reaction from Triynes;Organic Letters;2024-08-12
3. Tandem Vinylogous Aldol and Intramolecular [2 + 2] Cycloaddition toward Benzocyclobutenes by UV Light Photocatalysis;Organic Letters;2024-04-08
4. Computational workflow for steric assessment using the electric field-derived size;Electronic Structure;2023-10-16
5. Photochemical Isomerization of Cyclohept-1-ene-1-carbaldehyde: Strain-Release Cycloadditions and Ene Reactions;The Journal of Organic Chemistry;2023-08-14
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线，采集、加工和组织学术论文而形成的新型学术文献查询和分析系统，可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容，当前同舟云学术共收录了国内外主流学术期刊6万余种，收集的期刊论文及会议论文总量共计约1.5亿篇，并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询！咨询电话：010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3