Norbornene based-sulfide-stabilized silylium ions: synthesis, structure and application in catalysis-Reference-Cited by-同舟云学术

Norbornene based-sulfide-stabilized silylium ions: synthesis, structure and application in catalysis

Published:2022 Issue:4 Volume:51 Page:1407-1414
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dajnak Aymeric¹,Özpınar Gül Altınbaş²,Lenk Romaric¹,Saffon-Merceron Nathalie³,Baceiredo Antoine¹,Kato Tsuyoshi¹^ORCID,Müller Thomas²^ORCID,Maerten Eddy¹^ORCID

Affiliation:

1. Université de Toulouse, UPS, and CNRS, LHFA UMR 5069, 118 route de Narbonne, 31062 Toulouse, France

2. Institute of Chemistry, Carl von Ossietzky University of Oldenburg, D-26129 Oldenburg, Germany

3. Université de Toulouse, UPS, and CNRS, ICT UAR2599 118 route de Narbonne, 31062 Toulouse, France

Abstract

A sulfide-stabilized silylium ion has emerged as an easy-to-handle Lewis acid catalyst for Diels–Alder cycloadditions and hydrodefluorination reactions.

Funder

Agence Nationale de la Recherche

Centre National de la Recherche Scientifique

Université de Toulouse

Alexander von Humboldt-Stiftung

Deutsche Forschungsgemeinschaft

Niedersächsisches Ministerium für Wissenschaft und Kultur

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D1DT04009J

Reference66 articles.

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2. T.Müller , A model system for the generation of silyl cationic species of different reactivity and stability , in Organosilicon Chemistry , ed. V. N. Auner and J. Weis , Wiley-VCH , Weinheim , 2003 , pp. 34–44

3. Silylium ions in catalysis

4. A.Sekiguchi and V. Y.Lee , Organometallic compounds of low-coordinate Si, Ge, Sn and Pb , Wiley , Chichester , 2010

5. T.Müller , Silylium ions and stabilized silylium ions in Science of Synthesis , in Knowledge updates 2013/3 , Vol. ed. M. Oestreich , Thieme, G. Verlag KG , Stuttgart , 2013 , pp. 1–42

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