Imine-stabilized silylium ions: synthesis, structure and application in catalysis-Reference-Cited by-同舟云学术

Imine-stabilized silylium ions: synthesis, structure and application in catalysis

Published:2023 Issue:10 Volume:52 Page:3052-3058
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Dajnak Aymeric¹,Shi Limiao¹,Altınbaş Özpınar Gül²,Lenk Romaric¹,Saffon-Merceron Nathalie³,Baceiredo Antoine¹,Kato Tsuyoshi¹^ORCID,Müller Thomas²^ORCID,Maerten Eddy¹^ORCID

Affiliation:

1. Université de Toulouse, UPS, and CNRS, LHFA UMR 5069, 118 route de Narbonne, 31062 Toulouse, France

2. Institute of Chemistry, Carl von Ossietzky University, Oldenburg, D-26129 Oldenburg, Germany

3. Université de Toulouse, UPS, and CNRS, ICT UAR2599, 118 route de Narbonne, 31062 Toulouse, France

Abstract

Novel imine-stabilized silylium ions as efficient catalysts for the hydrosilylation and allylsilylation of carbonyl derivatives under mild conditions.

Funder

Ministère de l'Enseignement Supérieur et de la Recherche

Centre National de la Recherche Scientifique

Université de Toulouse

Alexander von Humboldt-Stiftung

Niedersächsische Ministerium für Wissenschaft und Kultur

Agence Nationale de la Recherche

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT00168G

Reference59 articles.

1. Crystallographic Evidence for a Free Silylium Ion

2. Silylium ions in catalysis

3. A.Sekiguchi and V. Y.Lee , Organometallic compounds of low-coordinate Si, Ge, Sn and Pb , 2010 , Wiley , Chichester

4. T.Müller , Silylium ions and stabilized silylium ions in Science of Synthesis , in Knowledge updates 2013/3 , ed. M. Oestreich and G. Thieme , Verlag KG , Stuttgart , 2013 , pp. 1–42

5. T.Müller , Silylium ions in Struct. Bond , ed. D. Scheschkewitz , 2014 , vol. 155 , pp. 107–162