Enantioselective and diastereoselective azo-coupling/iminium-cyclizations: a unified strategy for the total syntheses of (−)-psychotriasine and (+)-pestalazine B-Reference-Cited by-同舟云学术

Enantioselective and diastereoselective azo-coupling/iminium-cyclizations: a unified strategy for the total syntheses of (−)-psychotriasine and (+)-pestalazine B

Published:2015 Issue:6 Volume:6 Page:3599-3605
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Li Qi¹²³⁴⁵,Xia Tingting⁴⁵⁶⁷²,Yao Licheng⁴⁵⁶⁷²,Deng Haiteng⁸⁹⁷²³,Liao Xuebin⁴⁵⁶⁷²

Affiliation:

1. Tsinghua-Peking Centre for Life Sciences

2. Beijing 100084

3. China

4. Department of Pharmacology and Pharmaceutical Sciences

5. School of Medicine

6. Collaborative Innovation Center for Diagnosis and Treatment of Infectious Diseases

7. Tsinghua University

8. MOE Key Laboratory of Bioinformatics

9. School of Life Sciences

Abstract

We report a unified strategy for the total syntheses of (−)-psychotriasine and (+)-pestalazine B based on the advanced intermediates of 3α-amino-hexahydropyrrolo[2,3-b]indole.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC00338E

Reference75 articles.

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4. Total Synthesis of (±)-Psychotrimine

5. Determination of absolute configuration of trimeric indole alkaloid, psychotrimine, by first asymmetric total synthesis

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