Mechanistic insights into the ring-opening of biomass derived lactones-Reference-Cited by-同舟云学术

Mechanistic insights into the ring-opening of biomass derived lactones

Published:2016 Issue:16 Volume:6 Page:12932-12942
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Gupta Shelaka¹²³⁴⁵,Arora Rishabh¹²³⁴⁵,Sinha Nishant⁶⁷⁵,Alam Md. Imteyaz¹²³⁴⁵,Haider M. Ali¹²³⁴⁵

Affiliation:

1. Renewable Energy and Chemicals Laboratory

2. Department of Chemical Engineering

3. Indian Institute of Technology Delhi

4. New Delhi-110016

5. India

6. Dassault Systemes

7. Bangalore 560008

Abstract

Density functional theory calculations suggest the formation of an oxocarbenium ion intermediate in acid catalyzed ring-opening reactions of biomass derived lactones, which may play an important role in determining it's reactivity.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA22832H

Reference51 articles.

1. The critical role of heterogeneous catalysis in lignocellulosic biomass conversion

2. Catalytic conversion of biomass to biofuels

3. Biorenewable chemicals: Feedstocks, technologies and the conflict with food production

4. Mechanistic Insights into Ring-Opening and Decarboxylation of 2-Pyrones in Liquid Water and Tetrahydrofuran

5. A highly selective route to linear alpha olefins from biomass-derived lactones and unsaturated acids

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