Reduction of 2-<i>H</i>-substituted pyrrolinium cations: the carbon–carbon single bond in air stable 2,2′-bipyrrolidines as a two-electron-source-Reference-Cited by-同舟云学术

Reduction of 2-H-substituted pyrrolinium cations: the carbon–carbon single bond in air stable 2,2′-bipyrrolidines as a two-electron-source

Published:2023 Issue:44 Volume:59 Page:6698-6701
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Nayak Mithilesh Kumar¹^ORCID,Elvers Benedict J.²^ORCID,Mandal Debdeep¹,Das Ayan¹,Ramakrishnan Raghunathan¹^ORCID,Mote Kaustubh R.¹^ORCID,Schulzke Carola²^ORCID,Yildiz Cem Burak³^ORCID,Jana Anukul¹^ORCID

Affiliation:

1. Tata Institute of Fundamental Research Hyderabad, Gopanpally, Hyderabad-500046, Telangana, India

2. Institut für Biochemie, Universität Greifswald, Felix-Hausdorff-Straße 4, Greifswald D-17489, Germany

3. Department of Aromatic and Medicinal Plants, Aksaray University, Aksaray-68100, Türkiye

Abstract

2-Substituted pyrrolinium cations are reduced to air and moisture stable 2,2′-bipyrrolidines − the newly formed carbon–carbon single bond is electron-rich and may be utilized as an organic electron donor for various chemical transformations.

Funder

Department of Atomic Energy, Government of India

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC00891F

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