<i>Operando</i> characterization of rhodium catalyst degradation in hydroformylation-Reference-Cited by-同舟云学术

Operando characterization of rhodium catalyst degradation in hydroformylation

Published:2023 Issue:6 Volume:13 Page:1788-1801
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Gerlach Martin¹^ORCID,Jameel Froze²^ORCID,Seidel-Morgenstern Andreas¹³^ORCID,Stein Matthias²^ORCID,Hamel Christof¹^ORCID

Affiliation:

1. Faculty of Process and Systems Engineering, Chemical Process Engineering, Otto von Guericke University, Universitätsplatz 2, Magdeburg, Germany

2. Molecular Simulations and Design Group, Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstrasse 1, 39106 Magdeburg, Germany

3. Physical and Chemical Foundations of Process Engineering, Max Planck Institute for Dynamics of Complex Technical Systems, Sandtorstrasse 1, 39106 Magdeburg, Germany

Abstract

Kinetic studies combined with DFT calculations revealed degradation of catalyst to Rh-carbonyl clusters is responsible for the loss of regioselectivity in hydroformylation.

Funder

Deutsche Forschungsgemeinschaft

Max-Planck-Gesellschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CY/D2CY01807A

Reference50 articles.

1. Renewable Feedstocks: The Problem of Catalyst Deactivation and its Mitigation

2. Unifying views on catalyst deactivation