In situ FTIR spectroscopic investigations on rhodium carbonyl complexes in the absence of phosphorus ligands under hydroformylation conditions

Author:

Leidecker Benedict N.1ORCID,Fuentes Dilver Peña1ORCID,Wei Chunhong1ORCID,Sawall Mathias2,Neymeyr Klaus12ORCID,Franke Robert34ORCID,Börner Armin1,Kubis Christoph1ORCID

Affiliation:

1. Leibniz-Institut für Katalyse e. V., Albert-Einstein Str. 29a, 18059 Rostock, Germany

2. Institut für Mathematik, Universität Rostock, Ulmenstr. 59, 18057 Rostock, Germany

3. Evonik Oxeno GmbH & Co. KG, Paul-Baumann-Str. 1, 45772 Marl, Germany

4. Lehrstuhl für Theoretische Chemie, Ruhr-Universität Bochum, 44780 Bochum, Germany

Abstract

The composition of mixtures of rhodium carbonyl complexes in the absence of P-ligands under varying conditions relevant for hydroformylation have been studied by in situ FTIR spectroscopy.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Reference45 articles.

1. R.Franke and A.Börner , Hydroformylation: Fundamentals, Processes, and Applications in Organic Synthesis , Wiley-VCH , Weinheim , 2016

2. Rhodium Catalyzed Hydroformylation , ed. P. W. N. M. van Leeuwen , C. Claver , Kluwer , Dordrecht , 2002

3. Homogeneous Catalysis with Organometallic Compounds , ed. B. Cornils , W. A. Herrmann , M. Beller and R. Paciello , Wiley-VCH , Weinheim , 3rd edn, 2018

4. P. W. N. M.van Leeuwen and J. C.Chadwick , Homogeneous Catalysts , Wiley-VCH , Weinheim , 2011

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