A palladium-catalyzed approach to allenic aromatic ethers and first total synthesis of terricollene A

Author:

Huang Chaofan12345,Shi Fuchun67895,Cui Yifan67895,Li Can67895,Lin Jie12345,Liu Qi12345,Qin Anni12345,Wang Huanan12345,Wu Guolin12345,Wu Penglin12345,Xiao Junzhe67895ORCID,Xu Haibo67895,Yuan Yuan12345,Zhai Yizhan67895,Zheng Wei-Feng12345,Zheng Yangguangyan12345ORCID,Yu Biao67895,Ma Shengming12345ORCID

Affiliation:

1. Research Center for Molecular Recognition and Synthesis

2. Department of Chemistry

3. Fudan University

4. Shanghai 200433

5. P. R. China

6. State Key Laboratory of Organometallic Chemistry

7. Shanghai Institute of Organic Chemistry

8. Chinese Academy of Sciences

9. Shanghai 200032

Abstract

A palladium-catalyzed C–O bond formation reaction between phenols and allenylic carbonates to give 2,3-allenic aromatic ethers with decent to excellent yields under mild reaction conditions has been described.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference85 articles.

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3. SNAr Bases Macrocyclization via Biaryl Ether Formation: Application in Natural Product Synthesis

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5. Conformation‐Directed Macrocyclization Reactions

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