Coordination units of Mn2+ modulation toward tunable emission in zero-dimensional bromides for white light-emitting diodes

Author:

Zhou Guojun1ORCID,Ding Jialiang1,Jiang Xingxing2ORCID,Zhang Jian1ORCID,Molokeev Maxim S.345ORCID,Ren Qiqiong1,Zhou Jun6ORCID,Li Shili1,Zhang Xian-Ming17ORCID

Affiliation:

1. Key Laboratory of Magnetic Molecules and Magnetic Information Materials (Ministry of Education), School of Chemistry and Material Science, Shanxi Normal University, Taiyuan 030006, China

2. China Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

3. Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia

4. Department of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk 660041, Russia

5. Research and Development Department, Kemerovo State University, Kemerovo, 650000, Russia

6. Department of Physics, Beijng Technology and Business University, Beijing 100048, China

7. College of Chemistry & Chemical Engineering, Key Laboratory of Interface Science and Engineering in Advanced Material, Ministry of Education, Taiyuan University of Technology, Taiyuan, Shanxi 030024, P. R. China

Abstract

0D Mn2+-based bromides with [MnBr4]2− tetrahedral and [Mn3Br12]6− octahedral units are designed, which aims at clarifying the relationship between the coordination units of Mn2+ and tunable emissions.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Beijing Municipality

Russian Foundation for Basic Research

Shanxi Normal University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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