The involvement of the trisulfur radical anion in electron-catalyzed sulfur insertion reactions: facile synthesis of benzothiazine derivatives under transition metal-free conditions-Reference-Cited by-同舟云学术

The involvement of the trisulfur radical anion in electron-catalyzed sulfur insertion reactions: facile synthesis of benzothiazine derivatives under transition metal-free conditions

Published:2016 Issue:7 Volume:7 Page:4067-4072
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Gu Zheng-Yang¹²³⁴⁵,Cao Jia-Jia¹²³⁴⁵,Wang Shun-Yi¹²³⁴⁵,Ji Shun-Jun¹²³⁴⁵

Affiliation:

1. Key Laboratory of Organic Synthesis of Jiangsu Province

2. College of Chemistry

3. Chemical Engineering and Materials Science & Collaborative Innovation Center of Suzhou Nano Science and Technology

4. Soochow University

5. Suzhou 215123

Abstract

An efficient and practical synthesis of benzothiazine by K₂S initiated sulfur insertion reaction with enaminones via electron catalysis is developed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C6SC00240D

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5. Studies on antidiabetic agents. IX. A new aldose reductase inhibitor, AD-5467, and related 1,4-benzoxazine and 1,4-benzothiazine derivatives: Synthesis and biological activity.

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