Group VI metal complexes of tris(diphenylphosphinomethyl)phenylborate: modulation of ligand donation via coordination of M(CO)3 units at the borate phenyl substituent-Reference-Cited by-同舟云学术

Group VI metal complexes of tris(diphenylphosphinomethyl)phenylborate: modulation of ligand donation via coordination of M(CO)3 units at the borate phenyl substituent

Published:2015 Issue:8 Volume:44 Page:3737-3744
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fischer Paul J.¹²³⁴,Weberg Alexander B.¹²³⁴,Bohrmann Trent D.¹²³⁴,Xu Hanyue¹²³⁴,Young Victor G.¹⁵⁶⁴

Affiliation:

1. Department of Chemistry

2. Macalester College

3. Saint Paul

4. USA

5. University of Minnesota

6. Minneapolis

Abstract

Modulation of tris(diphenylphosphinomethyl)phenylborate donation to κ³-phosphine-bound fragments is inductively achieved by the coordination of 12-electron M(CO)₃ fragments at the borate phenyl substituent.

Funder

Camille and Henry Dreyfus Foundation

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03857F

Reference46 articles.

1. Synthesis of an anionic tridentate phosphinoborate and its reaction chemistry with Sn(II)

2. Silylene Extrusion from a Silane: Direct Conversion of Mes2SiH2 to an Iridium Silylene Dihydride

3. STRONGLY DONATING SCORPIONATE LIGANDS

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