Seventeen-electron chromium(i)tricarbonyltris(phosphine) complexes supported by tris(phosphinomethyl)phenylborates
Author:
Affiliation:
1. Department of Chemistry
2. Macalester College
3. Saint Paul
4. USA
5. University of Minnesota
6. Minneapolis
Abstract
Tris(diphenylphosphinomethyl)phenylborates permit isolation of remarkably thermally stable chromium(i)tricarbonyltris(phosphine) complexes, the first crystallographically characterized [Cr(CO)3P3]+ radicals.
Funder
Division of Chemistry
Camille and Henry Dreyfus Foundation
University of Minnesota
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03562A
Reference21 articles.
1. On the Failure To Observe Isotropic Electron Paramagnetic Resonance Spectra for Certain Chromium(I) Carbonyl Complexes
2. EPR Study of Photochemical Reactions of fac- and mer-[Cr(CO)3(η1-L2)(η2-L2)]+ (L2 = Bidentate Phosphine, Arsine, or Phosphonite Ligand)
3. Electrochemical and spectroscopic study of isomerization, cross-redox and self-exchange reactions in the [Cr(CO)3P3]+/0 redox system
4. Redox reactions of chromium tetracarbonyl and tricarbonyl complexes: thermodynamic, kinetic, and catalytic aspects of isomerization in the fac/mer-tricarbonyltris(trimethyl phosphite)chromium(1+/0) system
5. EPR Spectroscopic and Theoretical Study of Chromium(I) Carbonyl Phosphine and Phosphonite Complexes
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