Efficient synthesis of (E)-2-nitromethylcinnamatesviaphosphine-catalyzed tandem α-addition and 1,3-rearrangement-Reference-Cited by-同舟云学术

Efficient synthesis of (E)-2-nitromethylcinnamatesviaphosphine-catalyzed tandem α-addition and 1,3-rearrangement

Published:2019 Issue:16 Volume:6 Page:2872-2876
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Huang Guofei¹²³⁴⁵,Ren Xiaoyu¹²³⁴⁵,Jiang Chunhui¹²³⁴⁵,Wu Jia-Hong¹²³⁴⁵,Gao Guowei¹²³⁴⁵,Wang Tianli¹²³⁴⁵^ORCID

Affiliation:

1. Key Laboratory of Green Chemistry & Technology of Ministry of Education

2. College of Chemistry

3. Sichuan University

4. Chengdu 610064

5. P. R. China

Abstract

An efficient synthetic approach for accessing (E)-2-nitromethylcinnamatesviaa phosphine-promoted tandem reaction between substituted nitromethanes and alkynes has been developed.

Funder

National Natural Science Foundation of China

Recruitment Program of Global Experts

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/QO/C9QO00478E

Reference69 articles.

1. N. Ono , The Nitro Group in Organic Synthesis , Wiley-VCH , New York , 2001

2. Functionalized Nitroalkanes as Useful Reagents for Alkyl Anion Synthons

3. The Chemistry of Amino, Nitroso, Nitro and Related Groups , ed. S. Patai , Wiley , Chichester , 1996

4. Nitro and related groups

5. Recent synthetic developments in the nitro to carbonyl conversion (Nef reaction)

Cited by 11 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Advances in Organocatalytic Asymmetric Reactions Involving Thioesters;Acta Chimica Sinica;2023

2. NHC-catalyzed [3 + 3] cycloaddition of α-bromoenals with nitroketene aminals or nitroketene N,S-acetals: synthesis of nitro-containing dihydropyridin-2-ones;Organic & Biomolecular Chemistry;2023

3. Selective Synthesis of α‐Alkoxy Enones by α‐Addition of Alcohols to Alkynones Using 1,1,1,3,3,3‐Hexafluoroisopropanol and PPh ₃ as Co‐catalysts;European Journal of Organic Chemistry;2022-12-13

4. Density Functional Theory Study on the Mechanism of Organophosphine-Catalyzed [4+2] Cycloaddition Reaction;Chinese Journal of Organic Chemistry;2022

5. In situ phosphonium-containing Lewis base-catalyzed 1,6-cyanation reaction: a facile way to obtain α-diaryl and α-triaryl acetonitriles;Organic Chemistry Frontiers;2022