In situ phosphonium-containing Lewis base-catalyzed 1,6-cyanation reaction: a facile way to obtain α-diaryl and α-triaryl acetonitriles-Reference-Cited by-同舟云学术

In situ phosphonium-containing Lewis base-catalyzed 1,6-cyanation reaction: a facile way to obtain α-diaryl and α-triaryl acetonitriles

Published:2022 Issue:1 Volume:9 Page:156-162
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Tan Jian-Ping¹²,Chen Yuan²,Ren Xiaoyu²,Guo Yumeng¹,Yi Bing¹,Zhang Hongkui²,Gao Guowei²,Wang Tianli²^ORCID

Affiliation:

1. Hunan Province Key Laboratory of Environmental Catalysis and Waste Recycling, College of Materials and Chemical Engineering, Hunan Institute of Engineering, Xiangtan, 411104, P. R. China

2. Key Laboratory of Green Chemistry & Technology of Ministry of Education, College of Chemistry, Sichuan University 29 Wangjiang Road, Chengdu 610064, P. R. China

Abstract

A in situ phosphonium-containing catalyst and its successful application in promoting remote 1,6-cyanation reaction of p-QMs and fuchsones have been disclosed, providing a facile and direct access to both α-diaryl and α-triaryl acetonitriles.

Funder

National Key Research and Development Program of China

Natural Science Foundation of Hunan Province

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QO/D1QO01501J

Reference38 articles.

1. Development of asymmetric phosphine-promoted annulations of allenes with electron-deficient olefins and imines