Indirect evidence for a NiIII–oxyl oxidant in the reaction of a NiII complex with peracid-Reference-Cited by-同舟云学术

Indirect evidence for a NiIII–oxyl oxidant in the reaction of a NiII complex with peracid

Published:2018 Issue:1 Volume:47 Page:246-250
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pirovano Paolo¹²³⁴⁵,Berry Abigail R.¹²³⁴⁵,Swart Marcel⁶⁷⁸⁹¹⁰^ORCID,McDonald Aidan R.¹²³⁴⁵^ORCID

Affiliation:

1. School of Chemistry and CRANN/AMBER Nanoscience Institute

2. Trinity College Dublin

3. The University of Dublin

4. College Green

5. Dublin 2

6. ICREA

7. Pg. Lluís Companys 23

8. 08010 Barcelona

9. Spain

10. Institut de Química Computacional i Catálisi

Abstract

The oxidation of a Ni^II complex with m-CPBA is shown to promote the formation of a transient Ni^III–O˙ species. Methine C–H bond activation in the supporting ligand by this species led to a benzoxazine product.

Funder

H2020 European Research Council

Ministerio de Economía y Competitividad

Generalitat de Catalunya

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/DT/C7DT03316H

Reference44 articles.

1. Biologically inspired oxidation catalysis

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4. Catalyst design in oxidation chemistry; from KMnO4 to artificial metalloenzymes

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