Aromatic and aliphatic hydrocarbon hydroxylation <i>via</i> a formally Ni<sup>IV</sup>O oxidant-Reference-Cited by-同舟云学术

Aromatic and aliphatic hydrocarbon hydroxylation via a formally Ni^IVO oxidant

Published:2023 Issue:9 Volume:52 Page:2663-2671
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Heim Philipp¹^ORCID,Gericke Robert¹^ORCID,Spedalotto Giuseppe¹,Lovisari Marta¹,Farquhar Erik R.²^ORCID,McDonald Aidan R.¹^ORCID

Affiliation:

1. School of Chemistry and CRANN/AMBER Nanoscience Institute, Trinity College Dublin, The University of Dublin, College Green, Dublin 2, Ireland

2. Center for Synchrotron Biosciences, National Synchrotron Light Source II, Brookhaven, National Laboratory Case Western Reserve University, Upton, NY 11973, USA

Abstract

The reaction between NiII salts and m-CPBA can lead to a potent formally NiIVO oxidant capable of arene hydroxylation, which decays to yield a meta-stable NiIII-phenolate.

Funder

H2020 European Research Council

Science Foundation Ireland

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D2DT03949D

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