Double-stranded dimetallic helicates: assembling–disassembling driven by the CuI/CuII redox change and the principle of homochiral recognition-Reference-Cited by-同舟云学术

Double-stranded dimetallic helicates: assembling–disassembling driven by the CuI/CuII redox change and the principle of homochiral recognition

Published:2014 Issue:6 Volume:43 Page:1835-1847
ISSN:0306-0012
Container-title:Chem. Soc. Rev.
language:en
Short-container-title:Chem. Soc. Rev.

Author:

Boiocchi Massimo¹²³,Fabbrizzi Luigi⁴²³

Affiliation:

1. Centro Grandi Strumenti

2. Università di Pavia

3. 27100 Pavia, Italy

4. Dipartimento di Chimica

Abstract

Upon reduction of a mononuclear complex of Cu^II with a tetradentate ligand (a racemic mixture of the S,S and R,R enantiomers) two dicopper(i) double stranded helicates form, each one containing strands of the same chirality.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/CS/C3CS60428D

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