Double-stranded dimetallic helicates: assembling–disassembling driven by the CuI/CuII redox change and the principle of homochiral recognition
Author:
Affiliation:
1. Centro Grandi Strumenti
2. Università di Pavia
3. 27100 Pavia, Italy
4. Dipartimento di Chimica
Abstract
Upon reduction of a mononuclear complex of CuII with a tetradentate ligand (a racemic mixture of the S,S and R,R enantiomers) two dicopper(i) double stranded helicates form, each one containing strands of the same chirality.
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/CS/C3CS60428D
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