Helical fluxionality: numerical frustration drives concerted low-barrier screw motions of a tricopper cluster-Reference-Cited by-同舟云学术

Helical fluxionality: numerical frustration drives concerted low-barrier screw motions of a tricopper cluster

Published:2023 Issue:12 Volume:14 Page:3265-3269
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kim Heechan¹^ORCID,Shin Juhwan¹,Kim Seyong¹,Lee Dongwhan¹^ORCID

Affiliation:

1. Department of Chemistry, Seoul National University, 1 Gwanak-ro, Gwanak-gu, Seoul 08826, Korea

Abstract

An uneven distribution of ligand donor atoms and metal centers of a double-helical trinuclear complex drives a hitherto unknown type of fluxional motion taking a spiral path with an extraordinarily low energy barrier.

Funder

National Research Foundation of Korea

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC00851G

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