Molecular and electronic structures of donor-functionalized dysprosium pentadienyl complexes
Author:
Affiliation:
1. School of Chemistry
2. The University of Manchester
3. Manchester
4. UK
Abstract
The molecular structures of two dysprosium complexes of donor-functionalized pentadienyl ligands are described. Electronic structure calculations reveal that the W-shaped pentadienyl ligand strongly influences the orientation of the main magnetic axis of the ground Kramers doublets in both complexes.
Funder
Leverhulme Trust
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00346F
Reference46 articles.
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4. The coordination chemistry of 2,4-di( tert -butyl)pentadienyl revisited
5. Phosphine-Substituted (η5-Pentadienyl) Manganese Carbonyl Complexes: Geometric Structures, Electronic Structures, and Energetic Properties of the Associative Substitution Mechanism, Including Isolation of the Slipped η3-Pentadienyl Associative Intermediate
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