Synthesis and structures of fluoride-bridged dysprosium clusters: influence of fluoride ions on magnetic relaxation behaviors

Author:

Yuan Qiong1,Meng Yin-Shan2ORCID,Zhang Yi-Quan3ORCID,Gao Chen1,Liu Shan-Shan4ORCID,Wang Bing-Wu1ORCID,Gao Song15ORCID

Affiliation:

1. Beijing National Laboratory of Molecular Science, State Key Laboratory of Rare Earth Materials Chemistry and Applications, Beijing Key Laboratory for Magnetoelectric Materials and Devices, Peking University, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

2. State Key Laboratory of Fine Chemicals, Dalian University of Technology, 2 Linggong Rd., Dalian 116024, P. R. China

3. Jiangsu Key Laboratory for NSLSCS, School of Physical Science and Technology, Nanjing Normal University, Nanjing 210023, P. R. China

4. Beijing Key Laboratory of Fuels Cleaning and Advanced Catalytic Emission Reduction Technology, College of Chemical Engineering, Beijing Institute of Petrochemical Technology, Beijing 102617, PR China

5. School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, P. R. China

Abstract

The synthesis of fluoride-bridged 1Dy, 2Dy and hepta-nuclear 3Dy dysprosium complexes is reported here and a hydroxy-bridged dinuclear dysprosium complex 4Dy is synthesized for comparison.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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