Multi-nuclear silver(i) and copper(i) complexes: a novel bonding mode for bispyridylpyrrolides-Reference-Cited by-同舟云学术

Multi-nuclear silver(i) and copper(i) complexes: a novel bonding mode for bispyridylpyrrolides

Published:2014 Issue:6 Volume:43 Page:2458-2464
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Hu Xiao-Hui¹²³⁴⁵,Liang Yan¹²³⁴⁵,Li Chen¹²³⁴⁵,Yi Xiao-Yi¹²³⁴⁵

Affiliation:

1. Key Laboratory of Resources Chemistry of Nonferrous Metals

2. Ministry of Education

3. School of Chemistry and Chemical Engineering

4. Central South University

5. Changsha, P. R. China

Abstract

Reaction of deprotonated 2,5-bis(2′-pyridyl)pyrrole (HPDP_H) with AgOTf (where OTf⁻ = triflato) in THF readily yields a yellow triangular Ag₃ complex [(PDP_H)Ag]₃ (1), of which the av. Ag⋯Ag distance is 2.902 Å.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT52794H

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