Structural, spectroscopic and electronic properties of a family of face-shared bi-octahedral Ru25+/6+ complexes with a bridging 2,5-di(2-pyridyl)pyrrolide ligand-Reference-Cited by-同舟云学术

Structural, spectroscopic and electronic properties of a family of face-shared bi-octahedral Ru25+/6+ complexes with a bridging 2,5-di(2-pyridyl)pyrrolide ligand

Published:2020 Issue:21 Volume:49 Page:7053-7059
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Kang Shi-Rui¹²³⁴,Zhou Zi-Qin⁵⁶⁷⁸⁴,Xiong Chang-Feng¹²³⁴,Liu Bin⁵⁶⁷⁸⁴^ORCID,McGrady John E.⁹¹⁰¹¹¹²^ORCID,Obies Mohammed⁹¹⁰¹¹¹²¹³,Liu Chao¹²³⁴^ORCID,He Piao¹²³⁴^ORCID,Yi Xiao-Yi¹²³⁴^ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Central South University

3. Changsha

4. P. R. China

5. A key Laboratory of Synthetic and Natural Function Molecule Chemistry of Ministry of Education

6. College of Chemistry and Materials Science

7. Northwest University

8. Xi'an 710127

9. Department of Chemistry

10. University of Oxford

11. Oxford OX1 3QZ

12. UK

13. College of Pharmacy

Abstract

Herein, we found that nitrogen donor dpp⁻ligand is flexible and provides a platform for aggregation of Ru²⁺ and/or Ru³⁺ to give a new type of face-sharing bi-octahedra Ru₂⁵⁺ and Ru₂⁶⁺ dimer featuring of distinct metal–metal bond bond between two ruthenium centres.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shanxi Province

Higher Committee for Education Development in Iraq

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01325K

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