Non-directed aromatic C–H amination: catalytic and mechanistic studies enabled by Pd catalyst and reagent design-Reference-Cited by-同舟云学术

Non-directed aromatic C–H amination: catalytic and mechanistic studies enabled by Pd catalyst and reagent design

Published:2016 Issue:14 Volume:6 Page:5304-5310
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Bandara H. M. D.¹²³⁴,Jin D.¹²³⁴,Mantell M. A.¹²³⁴,Field K. D.¹²³⁴,Wang A.¹²³⁴,Narayanan R. P.¹²³⁴,Deskins N. A.⁵²³⁴,Emmert M. H.¹²³⁴

Affiliation:

1. Department of Chemistry and Biochemistry

2. Worcester Polytechnic Institute

3. Worcester

4. USA

5. Department of Chemical Engineering

Abstract

The systematic development of pyridine-type ligands and electrophilic amination reagents is described, which promote aromatic Pd catalyzed, non-directed C–H aminations.

Funder

National Institutes of Health

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CY/C6CY00457A

Reference38 articles.

1. Developing Ligands for Palladium(II)-Catalyzed C–H Functionalization: Intimate Dialogue between Ligand and Substrate

2. Remarkably High Reactivity of Pd(OAc)2/Pyridine Catalysts: Nondirected CH Oxygenation of Arenes

3. Platinum and Palladium Complexes Containing Cationic Ligands as Catalysts for Arene H/D Exchange and Oxidation

4. Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

5. Steric Control of Site Selectivity in the Pd-Catalyzed C–H Acetoxylation of Simple Arenes

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