Monomer-induced switching of stereoselectivity and limitation of chain growth in the polymerization of amine-containing para-substituted phenylacetylenes by [Rh(norbornadiene)Cl]2-Reference-Cited by-同舟云学术

Monomer-induced switching of stereoselectivity and limitation of chain growth in the polymerization of amine-containing para-substituted phenylacetylenes by [Rh(norbornadiene)Cl]2

Published:2017 Issue:37 Volume:8 Page:5761-5768
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Tian Yong¹²³⁴⁵,Li Xiaofang⁶⁷³⁸⁵^ORCID,Shi Jianbing¹²³⁴⁵,Tong Bin¹²³⁴⁵,Dong Yuping¹²³⁴⁵^ORCID

Affiliation:

1. Beijing Key Laboratory of Construction Tailorable Advanced Functional Materials and Green Applications

2. School of Materials Science and Engineering

3. Beijing Institute of Technology

4. Beijing 100081

5. China

6. Key Laboratory of Cluster Science of Ministry of Education

7. School of Chemistry and Chemical Engineering

8. Beijing

Abstract

In the presence of [Rh(nbd)Cl]₂ alone, amine-containing phenylacetylenes can serve as both a monomer and cocatalyst in the polymerization. Moreover, the stereo-selectivity of the products was controlled by pendant groups.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2017/PY/C7PY01201B

Reference46 articles.

1. Acetylenic Polymers: Syntheses, Structures, and Functions

2. Functional Polyacetylenes

3. Synthesis of high polymers from substituted acetylenes: exploitation of molybdenum- and tungsten-based catalysts

4. Stimuli-Responsive Polyacetylenes and Dendronized Poly(phenylacetylene)s

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