Polymerization of phenylacetylene catalyzed by rhodium(<scp>i</scp>) complexes with <i>N</i>-functionalized N-heterocyclic carbene ligands-Reference-Cited by-同舟云学术

Polymerization of phenylacetylene catalyzed by rhodium(i) complexes with N-functionalized N-heterocyclic carbene ligands

Published:2022 Issue:10 Volume:13 Page:1411-1421
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Angoy Marta¹,Jiménez M. Victoria¹^ORCID,Lahoz Fernando J.¹^ORCID,Vispe Eugenio¹,Pérez-Torrente Jesús J.¹^ORCID

Affiliation:

1. Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea–ISQCH, Universidad de Zaragoza–CSIC, Facultad de Ciencias, C/Pedro Cerbuna, 12, 50009 Zaragoza, Spain

Abstract

Rhodium complexes with functionalized NHC ligands catalyze the polymerization of phenylacetylene to give very high molar mass stereoregular polymers. Surprisingly, some chloro-complexes are much more active than related cationic precursors also.

Funder

Ministerio de Ciencia e Innovación

Gobierno de Aragón

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D1PY01650D

Reference65 articles.

1. Substituted Polyacetylenes: Synthesis, Properties, and Functions

2. Stimuli-Responsive Polyacetylenes and Dendronized Poly(phenylacetylene)s