Borataalkene or boratabenzene? Understanding the aromaticity of 9-borataphenanthrene anions and its central ring-Reference-Cited by-同舟云学术

Borataalkene or boratabenzene? Understanding the aromaticity of 9-borataphenanthrene anions and its central ring

Published:2020 Issue:41 Volume:44 Page:18069-18073
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Báez-Grez Rodrigo¹²³⁴⁵^ORCID,Pino-Rios Ricardo⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Computational and Theoretical Chemistry Group

2. Departamento de Ciencias Química

3. Facultad de Ciencias Exactas

4. Universidad Andres Bello

5. República 498

6. Laboratorio de Química teórica

7. Facultad de Química y Biología

8. Universidad de Santiago de Chile (USACH) Av. Libertador Bernardo O’Higgins 3363

9. Estación Central

10. Chile

Abstract

The recently isolated 1 is isoelectronic to 2 and shows reactivity in central ring that resembles both (cyclo)alkene and aromatic ring. Evaluation of local aromaticity reveal that central ring is best described as a non-aromatic following Clar’s rules.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/NJ/D0NJ03942J

Reference60 articles.

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