The Glidewell–Lloyd rule explains the local aromaticity and the relative stability of benzoborepin isomers-Reference-Cited by-同舟云学术

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The Glidewell–Lloyd rule explains the local aromaticity and the relative stability of benzoborepin isomers

Published:2024 Issue:24 Volume:48 Page:10969-10972
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Leyva-Parra Luis¹,Pino-Rios Ricardo²³^ORCID

Affiliation:

1. Facultad de Ingeniería y Arquitectura, Universidad Central de Chile, Santa Isabel 1186, Santiago, Chile

2. Química y Farmacia, Facultad de Ciencias de la Salud, Universidad Arturo Prat. Casilla 121, Iquique 1100000, Chile

3. Centro de Investigación Medicina de Altura – CEIMA, Universidad Arturo Prat. Casilla 121, Iquique 1100000, Chile

Abstract

Relative stability and local aromaticity of benzoborepine isomers have been studied using magnetic/electronic/geometric aromaticity criteria. Results shows the most stable isomer is also the most aromatic in agreement with the Glidewell–Lloyd rule.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ01638F

Reference43 articles.

1. Aromaticity of Annelated Borepins

2. Benzo- and Naphthoborepins: Blue-Emitting Boron Analogues of Higher Acenes

3. Functionalized Dibenzoborepins as Components of Small Molecule and Polymeric π-Conjugated Electronic Materials

4. Annulated Borepin-1-ol: Coordinative Control of Aromaticity and Photophysical Properties

5. Boron-Doped Molecules for Optoelectronics

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