The dual-catalyzed boryldifluoroallylation of alkynes: an efficient method for the synthesis of skipped gem-difluorodienes-Reference-Cited by-同舟云学术

The dual-catalyzed boryldifluoroallylation of alkynes: an efficient method for the synthesis of skipped gem-difluorodienes

Published:2020 Issue:15 Volume:56 Page:2340-2343
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Zhuo Kai-Feng¹²³⁴⁵,Xu Wen-Yan¹²³⁴⁵,Gong Tian-Jun¹²³⁴⁵^ORCID,Fu Yao¹²³⁴⁵^ORCID

Affiliation:

1. Hefei National Laboratory for Physical Sciences at the Microscale

2. iChEM

3. CAS Key Laboratory of Urban Pollutant Conversion

4. Anhui Province Key Laboratory of Biomass Clean Energy

5. University of Science and Technology of China

Abstract

The Cu/Pd-catalyzed boryldifluoroallylation of alkynes was achieved, providing the skipped gem-difluorodiene scaffolds with high regio- and stereoselectivity. An array of synthetic building blocks can be obtained via further transformations.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Chinese Academy of Sciences

Hefei Science Center, Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/C9CC08485A

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