The synergy effect of rare earth cations on local structure and PL emission in a Ce3+:REPO4(RE = La, Gd, Lu, Y) system-Reference-Cited by-同舟云学术

The synergy effect of rare earth cations on local structure and PL emission in a Ce3+:REPO4(RE = La, Gd, Lu, Y) system

Published:2017 Issue:24 Volume:46 Page:7888-7896
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Sun Congting¹²³⁴⁵^ORCID,Xue Dongfeng¹²³⁴⁵^ORCID

Affiliation:

1. State Key Laboratory of Rare Earth Resource Utilization

2. Changchun Institute of Applied Chemistry

3. Chinese Academy of Sciences

4. Changchun 130022

5. China

Abstract

The activation of P−O bonding that promotes the phase transition and enhances the PL emission of REPO₄under the synergy effect of rare earth cations is studied. Anion groups with lower site symmetry coordinated with rare earth cations favor 5d → 4f emission of Ce³⁺.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01375B

Reference40 articles.

1. Luminescence and scintillation properties of LuPO4-Ce nanoparticles

2. Concentration dependence of the Bi3+ luminescence in LnPO4 (Ln=Y3+, Lu3+)

3. NMR and ESR relaxation in Nd- and Gd-doped LaPO4: towards the accurate determination of the doping concentration