The Effect of Lu3+ Doping on the Structural Stability and Luminescence Performances of Gd3Al5O12:Dy Phosphors

Author:

Qian Huiyu1,Sun Zhigang1,Liang Tuanjie1,Wang Mengyao1,Lu Bin1ORCID,Chen Hongbing12,Jiang Linwen12

Affiliation:

1. School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211, China

2. Key Laboratory of Photoelectric Detection Materials and Devices of Zhejiang Province, Ningbo University, Ningbo 315211, China

Abstract

Transparent ceramics (Gd0.975−xLuxDy0.025)3Al5O12 (x = 0.2, 0.5, 0.975) are fabricated by vacuum sintering with the transmittance of ~60% at 583 nm. The doping of Lu3+ was beneficial to stabilize the garnet phase, and the best doping concentration was 20 at.%. All three (Gd, Lu)3Al5O12:Dy ceramics display typical Dy3+ emission, originating from 4F9/2 → 6HJ (J = 15/2, 13/2, 11/2) transition. Temperature-dependent luminescence spectra from 303.15 K to 603.15 K prove that the (Gd, Lu)3Al5O12:Dy ceramics had good thermal stability and could be an ideal yellow-emitting candidate in light-emitting diodes. The luminous efficiency of the encapsulated white LED lamp was found to be ~87.9 lm/W when the injection current was 600 mA. The transparent (Gd, Lu)3Al5O12:Dy ceramics show great application potential in various optical systems especially in the fields of luminescence and display.

Funder

Natural Science Foundation of China

Department of Education of Zhejiang Province

Natural Science Foundation of Ningbo Municipality

Publisher

MDPI AG

Subject

General Materials Science,Metals and Alloys

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