Reactivity of bulky Ln(ii) amidinates towards P4, As4, and As4S4-Reference-Cited by-同舟云学术

Reactivity of bulky Ln(ii) amidinates towards P4, As4, and As4S4

Published:2018 Issue:38 Volume:54 Page:4770-4773
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Schoo Christoph¹²³⁴,Bestgen Sebastian¹²³⁴^ORCID,Köppe Ralf¹²³⁴,Konchenko Serygey N.¹²³⁴⁵,Roesky Peter W.¹²³⁴^ORCID

Affiliation:

1. Institute of Inorganic Chemistry

2. Karlsruhe Institute of Technology

3. Karlsruhe 76131

4. Germany

5. Nikolaev Institute of Inorganic Chemistry SB RAS

Abstract

The reduction of P₄, As₄ and As₄S₄ (realgar) with [(DippForm)₂Ln(thf)₂] (Ln = Sm, Yb) led to the first, purely f-element containing inverse inorganic sandwich complexes [{(DippForm)₂Sm}₂(μ²-η⁴:η⁴-E₄)] (E = P, As) and the unusual species [{(DippForm)(DippForm-AsS₂)}Ln(thf)].

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC01519H

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