The energetic viability of an unexpected skeletal rearrangement in cyclooctatin biosynthesis-Reference-Cited by-同舟云学术

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The energetic viability of an unexpected skeletal rearrangement in cyclooctatin biosynthesis

Published:2015 Issue:41 Volume:13 Page:10273-10278
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Hong Young J.¹²³⁴,Tantillo Dean J.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Univeristy of California-Davis

3. Davis

4. USA

Abstract

Results of density functional theory calculations on possible mechanisms for formation of the diterpenoid cyclooctatin are described.

Funder

Directorate for Mathematical and Physical Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/OB/C5OB01785H

Reference36 articles.

1. Cyclooctatin, a new inhibitor of lysophospholipase, produced by Streptomyces melanosporofaciens MI614-43F2. Taxonomy, production, isolation, physico-chemical properties and biological activities.

2. The structure of cyclooctatin, a new inhibitor of lysophospholipase.

3. An Unusual Terpene Cyclization Mechanism Involving a Carbon-Carbon Bond Rearrangement

4. Cloning and Heterologous Expression of the Cyclooctatin Biosynthetic Gene Cluster Afford a Diterpene Cyclase and Two P450 Hydroxylases

5. Feasibility of Intramolecular Proton Transfers in Terpene Biosynthesis – Guiding Principles

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