A cavity-shaped <i>cis</i>-chelating P,N ligand for highly selective nickel-catalysed ethylene dimerisation-Reference-Cited by-同舟云学术

A cavity-shaped cis-chelating P,N ligand for highly selective nickel-catalysed ethylene dimerisation

Published:2022 Issue:30 Volume:51 Page:11226-11230
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Li Yang¹^ORCID,Pelzer Katrin¹^ORCID,Sechet Damien²,Creste Geordie¹^ORCID,Matt Dominique²^ORCID,Braunstein Pierre¹^ORCID,Armspach Dominique¹^ORCID

Affiliation:

1. Equipe Confinement Moléculaire et Catalyse, Institut de Chimie de Strasbourg, UMR 7177 CNRS, Université de Strasbourg, 4, rue Blaise Pascal, CS 90032, 67081 Strasbourg Cedex, France

2. Laboratoire de Chimie Inorganique Moléculaire et Catalyse, Institut de Chimie de Strasbourg, UMR 7177 CNRS, Université de Strasbourg, 4, rue Blaise Pascal, CS 90032, 67081 Strasbourg Cedex, France

Abstract

The presence of a cyclodextrin cavity in a chelating P,N ligand promotes the exclusive formation of 1 : 1 ligand/metal complexes. A Ni(ii) complex of the ligand is a very selective catalyst for ethylene dimerisation as a result of metal confinement.

Funder

China Scholarship Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT01553F

Reference54 articles.

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