Reactivity studies on [Cp′Fe(μ-I)]2: nitrido-, sulfido- and diselenide iron complexes derived from pseudohalide activation-Reference-Cited by-同舟云学术

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Reactivity studies on [Cp′Fe(μ-I)]2: nitrido-, sulfido- and diselenide iron complexes derived from pseudohalide activation

Published:2017 Issue:5 Volume:8 Page:4108-4122
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Reiners Matthias¹²³⁴,Maekawa Miyuki¹²³⁴^ORCID,Daniliuc Constantin G.¹²³⁴,Freytag Matthias¹²³⁴,Jones Peter G.¹²³⁴,White Peter S.⁵⁶⁷⁸,Hohenberger Johannes⁹¹⁰¹¹¹²⁴,Sutter Jörg⁹¹⁰¹¹¹²⁴,Meyer Karsten⁹¹⁰¹¹¹²⁴,Maron Laurent¹³¹⁴¹⁵¹⁶¹⁷,Walter Marc D.¹²³⁴^ORCID

Affiliation:

1. Technische Universität Braunschweig

2. Institut für Anorganische und Analytische Chemie

3. 38106 Braunschweig

4. Germany

5. University of North Carolina at Chapel Hill

6. Department of Chemistry

7. Chapel Hill

8. USA

9. University of Erlangen-Nürnberg

10. Department of Chemistry & Pharmacy

11. Inorganic Chemistry

12. 91058 Erlangen

13. Université de Toulouse

14. INSA-UPS-LPCNO

15. CNRS-LPCNO

16. F-31077 Toulouse

17. France

Abstract

Facile pseudohalide activation occurs in the reaction of SCN⁻, SeCN⁻and N₃⁻with the iron half-sandwich [Cp′Fe(μ-I)]₂.

Funder

National Science Foundation

Deutsche Forschungsgemeinschaft

Alexander von Humboldt-Stiftung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C7SC00570A

Reference106 articles.

1. High-valent iron phthalocyanine .mu.-nitrido dimers

2. Ground-State Singlet L3Fe-(μ-N)-FeL3 and L3Fe(NR) Complexes Featuring Pseudotetrahedral Fe(II) Centers

3. An FeVI Nitride: There Is Plenty of Room at the Top!

4. Structural and Spectroscopic Characterization of an Electrophilic Iron Nitrido Complex

5. Formation of Ammonia from an Iron Nitrido Complex

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