cis-Specific ring opening metathesis polymerisation (ROMP) of cyclic olefins using (pentafluorophenylimido)vanadium(v)-alkylidene, V(CHSiMe3)(NC6F5)[OC(CF3)3](PMe3)2

Author:

Nomura Kotohiro1234ORCID,Chaimongkolkunasin Sapanna1234

Affiliation:

1. Department of Chemistry

2. Tokyo Metropolitan University

3. Tokyo 192-0397

4. Japan

Abstract

Highly cis-specific (Z selective) ring opening metathesis polymerisation of cycloheptene has been demonstrated using V(CHSiMe3)(NC6F5)[OC(CF3)3](PMe3)2.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Reference60 articles.

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2. Olefin Metathesis: Theory and Practice , ed. K. Grela , John Wiley & Sons, Inc. , Hoboken, New Jersey, USA , 2014

3. Handbook of Metathesis , ed. R. H. Grubbs and A. G. Wenzel , Wiley-VCH , Weinheim, Germany , 2nd edn, 2015 , vol. 1

4. Homogeneous Metathesis Polymerization by Well-Defined Group VI and Group VIII Transition-Metal Alkylidenes:  Fundamentals and Applications in the Preparation of Advanced Materials

5. Handbook of Metathesis , ed. R. H. Grubbs , Wiley-VCH , Weinheim, Germany , 2003 , vol. 3

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