Vanadium(<scp>v</scp>) arylimido alkylidene N-heterocyclic carbene complexes containing fluorinated alkoxide or halogenated phenoxide ligands for the syndiospecific ROMP of cyclic olefins-Reference-Cited by-同舟云学术

Vanadium(v) arylimido alkylidene N-heterocyclic carbene complexes containing fluorinated alkoxide or halogenated phenoxide ligands for the syndiospecific ROMP of cyclic olefins

Published:2024 Issue:34 Volume:48 Page:14865-14872
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Nomura Kotohiro¹^ORCID,Kuwahara Shuko¹,Suthala Jirapa¹,Kawamoto Yuta¹,Shimoyama Daisuke¹,Buchmeiser Michael R.²³^ORCID

Affiliation:

1. Department of Chemistry, Tokyo Metropolitan University, 1-1 Minami Osawa, Hachioji, Tokyo 192-0927, Japan

2. Institute of Polymer Chemistry, University of Stuttgart, Pfaffenwaldring 55, 70569 Stuttgart, Germany

3. German Institutes of Textile and Fiber Research (DITF) Denkendorf, Körschtalstr. 26, D-73770 Denkendorf, Germany

Abstract

[V(N-2,6-Cl2C6H3)(CHSiMe3)(OC6X5)(NHC)] exhibited remarkable catalytic activities for ROMP of norbornene at 25 °C to afford ring-opened polymers not only with high cis-(93–98%) selectivity, but also with exclusive syndiotactic stereo-regularity.

Funder

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ02537G

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