Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy-Reference-Cited by-同舟云学术

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Revealing electrolyte oxidation via carbonate dehydrogenation on Ni-based oxides in Li-ion batteries by in situ Fourier transform infrared spectroscopy

Published:2020 Issue:1 Volume:13 Page:183-199
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Zhang Yirui¹²³⁴^ORCID,Katayama Yu⁵²³⁴⁶^ORCID,Tatara Ryoichi⁵²³⁴^ORCID,Giordano Livia¹²³⁴⁵,Yu Yang⁷²³⁴,Fraggedakis Dimitrios⁸²³⁴,Sun Jame Guangwen¹²³⁴^ORCID,Maglia Filippo⁹¹⁰¹¹^ORCID,Jung Roland⁹¹⁰¹¹,Bazant Martin Z.⁸²³⁴¹²^ORCID,Shao-Horn Yang¹²³⁴⁵^ORCID

Affiliation:

1. Department of Mechanical Engineering

2. Massachusetts Institute of Technology

3. Cambridge

4. USA

5. Research Laboratory of Electronics

6. Department of Applied Chemistry

7. Department of Material Science and Engineering

8. Department of Chemical Engineering

9. BMW Group

10. 80788 München

11. Germany

12. Department of Mathematics

Abstract

Carbonate oxidation via dehydrogenation on LiNi_0.8Co_0.1Mn_0.1O₂ at voltages as low as 3.8 V_Li was revealed by in situ FT-IR measurements.

Funder

Office of Science

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/EE/C9EE02543J

Reference126 articles.

1. Artificial solid-electrolyte interphase (SEI) for improved cycleability and safety of lithium–ion cells for EV applications

2. Precision Measurements of the Coulombic Efficiency of Lithium-Ion Batteries and of Electrode Materials for Lithium-Ion Batteries

3. Electrochemical Kinetics of SEI Growth on Carbon Black: Part I. Experiments

4. Electrochemical Kinetics of SEI Growth on Carbon Black: Part II. Modeling

5. Comparison of the structural and electrochemical properties of layered Li[NixCoyMnz]O2 (x = 1/3, 0.5, 0.6, 0.7, 0.8 and 0.85) cathode material for lithium-ion batteries

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