Redox-mediated formation of plutonium oxide nanoparticles

Author:

Romanchuk Anna Yu.123ORCID,Plakhova Tatiana V.123ORCID,Egorov Alexander V.123,Egorova Tolganay B.123,Dorovatovskii Pavel V.423ORCID,Zubavichus Yan V.423ORCID,Shiryaev Andrey A.12352,Kalmykov Stepan N.123ORCID

Affiliation:

1. Lomonosov Moscow State University

2. Moscow

3. Russia

4. National Research Centre “Kurchatov Institute”

5. Frumkin Institute of Physical Chemistry and Electrochemistry of Russian Academy of Science

Abstract

Precipitates formed by the neutralisation of Pu(iii), Pu(iv), Pu(v), and Pu(vi) solutions were characterised by HRTEM, SAXS, and XRD in the suspensions. PuO2 nanoparticles uniform in size (typical diameter around 2.5 nm) and phase composition were observed in all cases under equilibrium conditions.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference34 articles.

1. Behavior of plutonium in the environment

2. United States EPA , Drinking water regulations and health advisories , 1996

3. Plutonium(IV) polymers in aqueous and organic media

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