Insight into the structure–property relationship of UO2 nanoparticles-Reference-Cited by-同舟云学术

Insight into the structure–property relationship of UO2 nanoparticles

Published:2021 Issue:4 Volume:8 Page:1102-1110
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Gerber Evgeny¹²³⁴⁵^ORCID,Romanchuk Anna Yu.⁶⁷⁸⁹^ORCID,Weiss Stephan⁴⁵¹⁰¹¹^ORCID,Bauters Stephen¹²³⁴⁵^ORCID,Schacherl Bianca¹²¹³¹⁴¹¹^ORCID,Vitova Tonya¹²¹³¹⁴¹¹^ORCID,Hübner René⁴⁵¹⁰¹¹^ORCID,Shams Aldin Azzam Salim⁴⁵¹⁰¹¹,Detollenaere Dirk⁷¹⁵¹⁶¹⁷¹⁸,Banerjee Dipanjan¹⁹²⁰²³⁷^ORCID,Butorin Sergei M.²¹²²²³²⁴²⁵^ORCID,Kalmykov Stepan N.⁶⁷⁸⁹^ORCID,Kvashnina Kristina O.¹²³⁴⁵^ORCID

Affiliation:

1. The Rossendorf Beamline at ESRF – The European Synchrotron

2. 38043 Grenoble Cedex 9

3. France

4. Helmholtz-Zentrum Dresden-Rossendorf (HZDR)

5. Institute of Resource Ecology

6. Lomonosov Moscow State University

7. Department of Chemistry

8. 119991 Moscow

9. Russia

10. Dresden

11. Germany

12. Institute for Nuclear Waste Disposal (INE)

13. Karlsruhe Institute of Technology

14. D-76021 Karlsruhe

15. X-ray Imaging and Microspectroscopy Research Group

16. Ghent University

17. Ghent

18. Belgium

19. Dutch-Belgian Beamline (DUBBLE)

20. European Synchrotron Radiation Facility

21. Molecular and Condensed Matter Physics

22. Department of Physics and Astronomy

23. Uppsala University

24. Uppsala

25. Sweden

Abstract

We show that the structural and electronic properties of UO₂ NPs (2–3 nm) are similar to those of bulk UO₂ under inert conditions, with U(iv) as the dominating oxidation state, though NPs oxidize with time and under the X-ray beam.

Funder

Russian Foundation for Basic Research

Ministry of Education and Science of the Russian Federation

Swedish Research Council

H2020 European Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/QI/D0QI01140A

Reference77 articles.