Large structural changes upon protonation of Fe4S4 clusters: the consequences for reactivity
Author:
Affiliation:
1. School of Chemistry
2. University of New South Wales
3. Sydney 2052, Australia
4. Newcastle University
5. Newcastle upon Tyne, UK
Abstract
Recognition that protonation of μ3-S in [Fe4S4X4]2− clusters causes breaking of an S–Fe bond provides a kinetically consistent general mechanism for the acid-catalysed substitution reactions of [Fe4S4X4]2− clusters.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT01687D
Reference45 articles.
1. Structural and Functional Aspects of Metal Sites in Biology
2. Aconitase as Iron−Sulfur Protein, Enzyme, and Iron-Regulatory Protein
3. Iron-Sulfur Clusters: Nature's Modular, Multipurpose Structures
4. Great Metalloclusters in Enzymology
5. The Clusters of Nitrogenase: Synthetic Methodology in the Construction of Weak-Field Clusters
Cited by 14 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Structural insight into halide-coordinated [Fe4S4XnY4−n]2− clusters (X, Y = Cl, Br, I) by XRD and Mössbauer spectroscopy;Dalton Transactions;2023
2. Structural Enzymology of Nitrogenase Enzymes;Chemical Reviews;2020-06-15
3. Survey of the Geometric and Electronic Structures of the Key Hydrogenated Forms of FeMo-co, the Active Site of the Enzyme Nitrogenase: Principles of the Mechanistically Significant Coordination Chemistry;Inorganics;2019-01-15
4. What is the role of the isolated small water pool near FeMo‐co, the active site of nitrogenase?;The FEBS Journal;2018-06-07
5. X-ray crystal structures of [NHR3]2[Fe4S4X4] (X = PhS, R = Et or n Bu; X = Cl, R = n Bu): implications for sites of protonation in Fe–S clusters;Transition Metal Chemistry;2016-04-21
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3