Voltage clustering in redox-active ligand complexes: mitigating electronic communication through choice of metal ion

Author:

Zarkesh Ryan A.123,Ichimura Andrew S.4563,Monson Todd C.173,Tomson Neil C.89103ORCID,Anstey Mitchell R.123811

Affiliation:

1. Sandia National Laboratories

2. Livermore

3. USA

4. Department of Chemistry & Biochemistry

5. San Francisco State University

6. San Francisco

7. Albuquerque

8. Department of Chemistry

9. University of Pennsylvania

10. Philadelphia

11. Davidson College

Abstract

Homoleptic bis(imino)acenaphthene complexes of aluminum, chromium, and gallium were synthesized, characterized and modeled to compare the orbital contributions of main group elements and transition metals in ligand-based redox events toward increasing energy density of battery electrolytes.

Funder

University of Pennsylvania

San Francisco State University

Sandia National Laboratories, National Nuclear Security Administration

Research and Development

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference28 articles.

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