Alkaline quinone flow battery

Author:

Lin Kaixiang1,Chen Qing2,Gerhardt Michael R.2,Tong Liuchuan1,Kim Sang Bok1,Eisenach Louise3,Valle Alvaro W.3,Hardee David1,Gordon Roy G.12,Aziz Michael J.2,Marshak Michael P.12

Affiliation:

1. Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, MA 02138, USA.

2. Harvard John A. Paulson School of Engineering and Applied Sciences, 29 Oxford Street, Cambridge, MA 02138, USA.

3. Harvard College, Cambridge, MA 02138, USA.

Abstract

A solution for scalable-flow batteries Flow batteries, in which the redox active components are held in tanks separate from the active part of the cell, offer a scalable route for storing large quantities of energy. A challenge for their large-scale development is to avoid formulations that depend on toxic transition metal ions. Lin et al. show that quinones can be dissolved in alkaline solutions and coupled with ferricyanides to make a flow cell battery (see the Perspective by Perry). This gives scope for developing flow cells with very low costs, high efficiencies at practical power densities, simplicity of operation, and inherent safety. Science , this issue p. 1529 ; see also p. 1452

Funder

U.S. Department of Energy Advanced Research Projects Agency–Energy

Harvard John A. Paulson School of Engineering and Applied Sciences

Publisher

American Association for the Advancement of Science (AAAS)

Subject

Multidisciplinary

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