Binuclear coordination complex of open merocyanine form of photochromic spiropyran with MnII(hfac)2 having high spin (S = 5) ground state-Reference-Cited by-同舟云学术

Binuclear coordination complex of open merocyanine form of photochromic spiropyran with Mn^II(hfac)₂ having high spin (S = 5) ground state

Published:2023 Issue:11 Volume:47 Page:5470-5476
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Osipov Nikita G.¹^ORCID,Faraonov Maxim A.¹^ORCID,Shestakov Alexander F.¹,Mikhailenko Maxim V.¹,Kuzmin Alexey V.²,Khasanov Salavat S.²,Otsuka Akihiro³^ORCID,Yamochi Hideki³^ORCID,Kitagawa Hiroshi³^ORCID,Konarev Dmitri V.¹^ORCID

Affiliation:

1. Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry RAS, Chernogolovka, Moscow region, 142432, Russia

2. Institute of Solid State Physics RAS, Chernogolovka, Moscow region, 142432, Russia

3. Division of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto, 606-8502, Japan

Abstract

The interaction of 1,3,3-trimethylindolino-β-naphthopyrylospiran (TMI-NPS) with manganese(ii) hexafluoroacetylacetonate yields crystals of {MnII(hfac)2 (μ2-TMI-NPS)}2 (1) in which Mn(ii) atoms are bridged by oxygen atoms of ring-opened TMS-BPI into the dimer.

Funder

Russian Science Foundation

Ministry of Science and Higher Education of the Russian Federation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ00058C

Reference41 articles.

1. Photo-, Thermo-, Solvato-, and Electrochromic Spiroheterocyclic Compounds

2. Light-controlled molecular switches based on bistable spirocyclic organic and coordination compounds

3. Advances in Spiropyrans/Spirooxazines and Applications Based on Fluorescence Resonance Energy Transfer (FRET) with Fluorescent Materials

4. Factors Influencing Photochromism of Spiro-Compounds Within Polymeric Matrices

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1. Slow magnetic relaxation in a complex of photochromic spiropyran in a merocyanine form and cobalt(ii) hexafluoroacetylacetonate;Dalton Transactions;2024

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