A general benzylic C–H activation and C–C coupling reaction of zirconocenes mediated by C–N bond cleavage in tert-butylisocyanide – unusual formation of iminoacyl complexes-Reference-Cited by-同舟云学术

A general benzylic C–H activation and C–C coupling reaction of zirconocenes mediated by C–N bond cleavage in tert-butylisocyanide – unusual formation of iminoacyl complexes

Published:2019 Issue:44 Volume:48 Page:16525-16533
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Arndt Perdita¹²³,Reiß Melanie¹²³,Spannenberg Anke¹²³,Schünemann Claas¹²³,Reiß Fabian¹²³^ORCID,Beweries Torsten¹²³^ORCID

Affiliation:

1. Leibniz-Institut für Katalyse e.V. an der Universität Rostock

2. Rostock

3. Germany

Abstract

Reactions of the zirconocene alkyne complex [rac-(ebthi)Zr(η²-Me₃SiC₂SiMe₃)] (rac-(ebthi) = rac-1,2-ethylene-1,1′-bis(η⁵-tetrahydroindenyl)) with tert-butylisocyanide and methylbenzenes were investigated.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03120K

Reference51 articles.

1. Recent advances in the chemistry of heterometallacycles of group 4 metallocenes

2. Metal-Mediated and Metal-Catalyzed Reactions of Isocyanides

3. Base Metal Catalyzed Isocyanide Insertions

4. Reactivity studies of the zirconium-induced insertion of isonitriles into a 1-sila-3-zirconacyclobutane ring. Structural and chemical evidence of carbenium-like intermediates for the intramolecular 1,2-silyl shift and reductive coupling reactions

5. Migratory Insertion of an Isocyanide into 1-Zirconacyclopent-3-ynes

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Reactions of Titanium- and Zirconium-Based 1-Metallacyclobuta-2,3-diene Complexes with Diazenes: N═N Bond Cleavage versus N–C Bond Formation and Dearomatization;Organometallics;2024-06-18

2. Acetylene complexes of metallocenes of titanium, zirconium and hafnium. I. Synthesis, structure, and spectral characteristics;Coordination Chemistry Reviews;2023-10

3. Selective 1,2-insertion of carbodiimides and substrate-divergent silyl group migration at 1-metallacyclobuta-2,3-dienes;Inorganic Chemistry Frontiers;2023

4. Studies on the Catalytic Activities of Cp2ZrCl2 in Olefin Polymerizations that was In-Situ Synthesized or Adsorbed on Organosilaneized Surface of Spherical Silica Gel;Silicon;2022-06-13

5. 1-Zirconacyclobuta-2,3-dienes: synthesis of organometallic analogs of elusive 1,2-cyclobutadiene, unprecedented intramolecular C–H activation, and reactivity studies;Chemical Science;2021