Integration of accessible secondary metal sites into MOFs for H2S removal
Author:
Affiliation:
1. Department of Inorganic Chemistry
2. Dresden University of Technology
3. 01069 Dresden, Germany
4. Fraunhofer Institute for Material and Beam Technology (IWS) Dresden
5. 01277 Dresden, Germany
Abstract
2,2′-Bipyridine-5,5′-dicarboxylic acid (H2bipy) was utilized for the synthesis of a zirconium based MOF isoreticular to UiO-67. The chelating bipyridine moiety was used for postsynthetic functionalization of the MOF with different metal salts giving materials with good performance in capture of toxic H2S.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/QI/C3QI00093A
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