The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh4(CO)12] and [Rh6(CO)16]-Reference-Cited by-同舟云学术

The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh4(CO)12] and [Rh6(CO)16]

Published:2015 Issue:37 Volume:44 Page:16602-16610
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Johnson Brian F. G.¹²³

Affiliation:

1. University Chemical Laboratory

2. Cambridge

3. UK

Abstract

The Ligand Polyhedral Model (LPM) is applied to the carbonyl scrambling observed on the NMR timescale for the two cluster carbonyls [Rh₄(CO)₁₂] and [Rh₆(CO)₁₆].

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03360D

Reference30 articles.

1. Stereochemical nonrigidity of [Rh6(CO)15L] clusters in solutionElectronic supplementary information (ESI) available; the relationship between the rate of S-type exchange in [Rh6(CO)15(PR3)] and the pKaâ€² values of the phosphine ligand. See http://www.rsc.org/suppdata/dt/b1/b101962g/

2. CO fluxionality in Rh4(CO)12 and Rh6(CO)16

3. A Solution to the Structural Dilemma of Co4(CO)12Based on Valence Tautomerism and Steric Nonrigidity

4. The structures of simple binary carbonyls

5. The nature of [Fe3(CO)12] in solution

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. ChemInform Abstract: The Ligand Polyhedral Model Approach to the Mechanism of Complete Carbonyl Exchange in [Rh4(CO)12] and [Rh6(CO)16];ChemInform;2015-10-22

2. Comment on “The ligand polyhedral model approach to the mechanism of complete carbonyl exchange in [Rh4(CO)12] and [Rh6(CO)16]” by Brian F. G. Johnson, Dalton Transactions, 2015, 44, DOI: 10.1039/C4DT03360D;Dalton Transactions;2015